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Naphthenic acid (CAS: ) (NAs)is the name for an unspecific mixture of several cyclopentyl and cyclohexyl carboxylic acids with molecular weight of 120 to well over 700 atomic mass units. The main fraction are carboxylic acids with a carbon backbone of 9 to 20 carbons. McKee et al. claim that "naphthenic acids (NAs) are primarily cycloaliphatic carboxylic acids with 10 to 16 carbons."〔 Salts of naphthenic acids, which are naphthenates, are widely used as hydrophobic sources of metal ions in diverse applications.〔 Aluminium salts of naphthenic acid and palmitic acid were combined during World War II to produce napalm. The word "napalm" is derived from the words naphthenic acid and palmitic acid. ==Preparation and occurrence== They are obtained by oxidation of the naphtha fraction of the crude oil refining. The composition varies with the crude oil composition and the conditions during refining and oxidation. Naphthenic acids are present in crude oil. Fractions that are rich in naphthenic acids can cause corrosion damage to oil refinery equipment; the phenomenon of ''naphthenic acid corrosion'' (NAC) has therefore been well researched. Crude oils with a high content of naphthenic acids are often referred to as high total acid number (TAN) crude oils or high acid crude oil (HAC). Naphthenic acids are the major contaminant in water produced from the extraction of oil from Athabasca oil sands (AOL). Naphthenic acids have both acute and chronic toxicity to fish and other organisms.〔 In their oft-cited article published in ''Toxicological Sciences'' Rogers et al. stated that "naphthenic acids are the most significant environmental contaminants resulting from petroleum extraction from oil sands deposits." They found that "under worst-case exposure conditions, acute toxicity is unlikely in wild mammals exposed to naphthenic acids in AOS tailings pond water, but repeated exposure may have adverse health effects." Naphthenic acids are present in Athabasca oil sands (AOL) tailings pond water (TPW) at an estimated concentration of 81 mg/l.〔 In their 2002 article cited over 100 times, Rogers et al. reported on a solvent-based laboratory bench procedure developed to "efficiently extract naphthenic acids from bulk volumes of Athabasca oil sands tailings pond water (TPW)." Using Organization for Economic Cooperation and Development () protocols for testing toxicity, McKee et al. (2014) argued that based on their studies refined NAs when consumed orally were not acutely genotoxic to mammals. However, damage induced by NAs while transient in acute or discontinuous exposure, may be cumulative in repeated exposure.〔 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「naphthenic acid」の詳細全文を読む スポンサード リンク
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